Dichlorprop | CAS#120-36-5 |

Dichlorprop
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WARNING: This product is for research use only, not for human or veterinary use.

MedKoo CAT#: 591268

CAS#: 120-36-5

Description: Dichlorprop is a chlorophenoxy herbicide similar in structure to 2,4-D that is used to kill annual and perennial broadleaf weeds.

Chemical Structure

Dichlorprop

CAS# 120-36-5

Instruction

Theoretical Analysis

MedKoo Cat#: 591268
Name: Dichlorprop
CAS#: 120-36-5
Chemical Formula: C9H8CL2O3
Exact Mass: 233.99
Molecular Weight: 235.060
Elemental Analysis: C, 45.99; H, 3.43; Cl, 30.16; O, 20.42

Price and Availability

Size	Price	Availability	Quantity
25g	USD 350	2 weeks
Bulk inquiry Welcome, Customer: Please do not inquire quote if your intended use is for a patient since our products are for research use and for chemical synthesis use, not for human use . For in-stock products, we listed price in the web page. You may inquire prices for which sizes were not listed. If no price is listed, this means the product is not in stock at the moment, which may be available via custom synthesis. For cost-effective reason, minimum order of 1g is requested (typically very expensive). The lead time is usually 2-4 months. Quote of less than 1g will not be provided. MedKoo may not offer quote for below reasons: (1) current available synthetic method appears to be extremely expensive which is obviously not affordable to most customers; (2) Key raw material to make the product is temporally not available; (3) DEA controlled substances; (4) the product is under patent protection in customer’s country.

Synonym: Dichlorprop; NSC39624; NSC-39624; NSC39624

IUPAC/Chemical Name: Propanoic acid, 2-(2,4-dichlorophenoxy)-

InChi Key: MZHCENGPTKEIGP-UHFFFAOYSA-N

InChi Code: InChI=1S/C9H8Cl2O3/c1-5(9(12)13)14-8-3-2-6(10)4-7(8)11/h2-5H,1H3,(H,12,13)

SMILES Code: CC(OC1=CC=C(Cl)C=C1Cl)C(O)=O

Appearance: Solid powder

Purity: >98% (or refer to the Certificate of Analysis)

Shipping Condition: Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition: Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).

Solubility: Soluble in DMSO

Shelf Life: >2 years if stored properly

Drug Formulation: This drug may be formulated in DMSO

Stock Solution Storage: 0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code: 2934.99.9001

More Info:

Instruction:

View handling instruction

Biological target:
In vitro activity:
In vivo activity:

Preparing Stock Solutions

The following data is based on the product molecular weight 235.06 Batch specific molecular weights may vary from batch to batch due to the degree of hydration, which will affect the solvent volumes required to prepare stock solutions.

Concentration / Solvent Volume / Mass	1 mg	5 mg	10 mg
1 mM	1.15 mL	5.76 mL	11.51 mL
5 mM	0.23 mL	1.15 mL	2.3 mL
10 mM	0.12 mL	0.58 mL	1.15 mL
50 mM	0.02 mL	0.12 mL	0.23 mL

Formulation protocol:
In vitro protocol:
In vivo protocol:

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1: Matamoros V, Franco J. Assessing the use of sand, peat soil, and pine bark for the attenuation of polar pesticides from agricultural run-off: a bench-scale column experiment. Environ Sci Pollut Res Int. 2018 May 11. doi: 10.1007/s11356-018-2213-x. [Epub ahead of print] PubMed PMID: 29752670.

2: Chen Z, Wang J, Chen H, Wen Y, Liu W. Enantioselective Phytotoxicity of Dichlorprop to Arabidopsis thaliana: The Effect of Cytochrome P450 Enzymes and the Role of Fe. Environ Sci Technol. 2017 Oct 17;51(20):12007-12015. doi: 10.1021/acs.est.7b04252. Epub 2017 Sep 27. PubMed PMID: 28906105.

3: Chen Z, Wang J, Chen S, Wen Y. Enantioselective disturbance of chiral herbicide dichlorprop to nitrogen metabolism of Arabidopsis thaliana: Regular analysis and stable isotope attempt. Sci Total Environ. 2017 Dec 15;603-604:533-540. doi: 10.1016/j.scitotenv.2017.06.037. Epub 2017 Jun 20. PubMed PMID: 28645051.

4: Steinborn A, Alder L, Spitzke M, Dörk D, Anastassiades M. Development of a QuEChERS-Based Method for the Simultaneous Determination of Acidic Pesticides, Their Esters, and Conjugates Following Alkaline Hydrolysis. J Agric Food Chem. 2017 Feb 15;65(6):1296-1305. doi: 10.1021/acs.jafc.6b05407. Epub 2017 Feb 7. PubMed PMID: 28099798.

5: Franco J, Matamoros V. Mitigation of polar pesticides across a vegetative filter strip. A mesocosm study. Environ Sci Pollut Res Int. 2016 Dec;23(24):25402-25411. doi: 10.1007/s11356-016-7516-1. Epub 2016 Oct 2. PubMed PMID: 27696199.

6: Jin B, Rolle M. Joint interpretation of enantiomer and stable isotope fractionation for chiral pesticides degradation. Water Res. 2016 Nov 15;105:178-186. doi: 10.1016/j.watres.2016.08.057. Epub 2016 Aug 30. PubMed PMID: 27619494.

7: Feng X, Yu J, Pan L, Song G, Zhang H. Dissipation and Residues of Dichlorprop-P and Bentazone in Wheat-Field Ecosystem. Int J Environ Res Public Health. 2016 May 26;13(6). pii: E534. doi: 10.3390/ijerph13060534. PubMed PMID: 27240385; PubMed Central PMCID: PMC4923991.

8: Chen Z, Chen H, Zou Y, Wen Y. Stomatal behaviors reflect enantioselective phytotoxicity of chiral herbicide dichlorprop in Arabidopsis thaliana. Sci Total Environ. 2016 Aug 15;562:73-80. doi: 10.1016/j.scitotenv.2016.03.205. Epub 2016 Apr 17. PubMed PMID: 27092421.

9: Feld L, Nielsen TK, Hansen LH, Aamand J, Albers CN. Establishment of Bacterial Herbicide Degraders in a Rapid Sand Filter for Bioremediation of Phenoxypropionate-Polluted Groundwater. Appl Environ Microbiol. 2015 Nov 20;82(3):878-87. doi: 10.1128/AEM.02600-15. Print 2016 Feb 1. PubMed PMID: 26590282; PubMed Central PMCID: PMC4725289.

10: Epp JB, Alexander AL, Balko TW, Buysse AM, Brewster WK, Bryan K, Daeuble JF, Fields SC, Gast RE, Green RA, Irvine NM, Lo WC, Lowe CT, Renga JM, Richburg JS, Ruiz JM, Satchivi NM, Schmitzer PR, Siddall TL, Webster JD, Weimer MR, Whiteker GT, Yerkes CN. The discovery of Arylex™ active and Rinskor™ active: Two novel auxin herbicides. Bioorg Med Chem. 2016 Feb 1;24(3):362-71. doi: 10.1016/j.bmc.2015.08.011. Epub 2015 Aug 19. PubMed PMID: 26321602.

11: Kerchev P, Mühlenbock P, Denecker J, Morreel K, Hoeberichts FA, Van Der Kelen K, Vandorpe M, Nguyen L, Audenaert D, Van Breusegem F. Activation of auxin signalling counteracts photorespiratory H2O2-dependent cell death. Plant Cell Environ. 2015 Feb;38(2):253-65. PubMed PMID: 26317137.

12: Paszko T, Muszyński P, Materska M, Bojanowska M, Kostecka M, Jackowska I. Adsorption and degradation of phenoxyalkanoic acid herbicides in soils: A review. Environ Toxicol Chem. 2016 Feb;35(2):271-86. doi: 10.1002/etc.3212. Epub 2016 Jan 8. Review. PubMed PMID: 26292078.

13: Todoroki K, Ishii Y, Ide T, Min JZ, Inoue K, Huang X, Zhang W, Hamashima Y, Toyo'oka T. Advanced dress-up chiral columns: New removable chiral stationary phases for enantioseparation of chiral carboxylic acids. Anal Chim Acta. 2015 Jul 2;882:101-11. doi: 10.1016/j.aca.2015.03.037. Epub 2015 Mar 27. PubMed PMID: 26043097.

14: Sura S, Waiser MJ, Tumber V, Raina-Fulton R, Cessna AJ. Effects of a herbicide mixture on primary and bacterial productivity in four prairie wetlands with varying salinities: an enclosure approach. Sci Total Environ. 2015 Apr 15;512-513:526-539. doi: 10.1016/j.scitotenv.2015.01.064. Epub 2015 Jan 31. PubMed PMID: 25644848.

15: Raeppel C, Fabritius M, Nief M, Appenzeller BM, Briand O, Tuduri L, Millet M. Analysis of airborne pesticides from different chemical classes adsorbed on Radiello® Tenax® passive tubes by thermal-desorption-GC/MS. Environ Sci Pollut Res Int. 2015 Feb;22(4):2726-34. doi: 10.1007/s11356-014-3534-z. Epub 2014 Sep 11. PubMed PMID: 25205153.

16: Benfeito S, Silva T, Garrido J, Andrade PB, Sottomayor MJ, Borges F, Garrido EM. Effects of chlorophenoxy herbicides and their main transformation products on DNA damage and acetylcholinesterase activity. Biomed Res Int. 2014;2014:709036. doi: 10.1155/2014/709036. Epub 2014 Mar 27. PubMed PMID: 24795892; PubMed Central PMCID: PMC3985176.

17: Zhou H, Wang X, Zhou Y, Yao H, Ahmad F. Evaluation of the toxicity of ZnO nanoparticles to Chlorella vulgaris by use of the chiral perturbation approach. Anal Bioanal Chem. 2014 Jun;406(15):3689-95. doi: 10.1007/s00216-014-7773-0. Epub 2014 Apr 22. PubMed PMID: 24752692.

18: Tunç S, Duman O, Soylu I, Kancı Bozoğlan B. Study on the bindings of dichlorprop and diquat dibromide herbicides to human serum albumin by spectroscopic methods. J Hazard Mater. 2014 May 30;273:36-43. doi: 10.1016/j.jhazmat.2014.03.022. Epub 2014 Mar 25. PubMed PMID: 24709480.

19: Jammer S, Voloshenko A, Gelman F, Lev O. Chiral and isotope analyses for assessing the degradation of organic contaminants in the environment: Rayleigh dependence. Environ Sci Technol. 2014 Mar 18;48(6):3310-8. doi: 10.1021/es4039209. Epub 2014 Feb 26. PubMed PMID: 24471759.

20: Levi S, Hybel AM, Bjerg PL, Albrechtsen HJ. Stimulation of aerobic degradation of bentazone, mecoprop and dichlorprop by oxygen addition to aquifer sediment. Sci Total Environ. 2014 Mar 1;473-474:667-75. doi: 10.1016/j.scitotenv.2013.12.061. Epub 2014 Jan 8. PubMed PMID: 24412734.

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